Peel and devein shrimp; set aside. Drain pineapple chunks, reserving 1/4 cup juice. Set pineapple aside. Combine reserved pineapple juice, Italian dressing, tomato sauce, sugar, and mustard in a shallow dish; mix well. Add shrimp, tossing gently to coat. Cover and marinate 2 hours in the refrigerator, stirring occasionally. Remove shrimp from marinade, reserving marinade. Alternate shrimp, pineapple and green pepper on 4 skewers. Grill over medium-hot coals 3 to 4 minutes on each side or until done, basting with marinade. Serve over rice with hot marinade.
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